The hit ITV program is taking on Loose Women, The Chase and The Repair Shop in the Daytime category, while Alison Hammond will be hoping to be named best TV presenter.
Sadly, not all the stars nominated for awards will be at the ceremony, with both the late Paul O'Grady and Dame Deborah in the running to be posthumously recognised for their respective TV projects before their death.
It’s a nearly three-hour ceremony, with the live broadcast concluding at 10.30pm. The event will also be live-streamed via the ITV Hub.
There will also be lots of individual clips of key moments throughout the night posted to the National Television Awards’ official social media channels.
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Pixie Lott cradled her growing baby bumpCredit: Rex
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Joe Swash and Stacey Solomon were in attendance tooCredit: Rex
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Emma Willis flashed her bra in a white blazer suitCredit: Rex
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Ant & Dec matched in black tuxedosCredit: Rex
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AJ Odudu caught the eye in CostarellosCredit: Getty
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Mollie King wowed in a Victoria Beckham ensembleCredit: Rex
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Michelle Keegan never fails to look incredibleCredit: Rex
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Piers Morgan and Dermot O'Leary caught up at the eventCredit: Rex
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Georgia Kousoulou commanded attentionCredit: Rex
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Lizzie Cundy put on a breathtaking display in a red dressCredit: Getty
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Mark Labbett and Hayley Palmer put on a cosy displayCredit: Rex
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Davina McCall flashed her cleavage in a black jumpsuitCredit: Rex
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Katherine Ryan looked stunning in a pink gownCredit: PA
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Katherine Ryan posed on the red carpetCredit: Rex
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Kate Garraway looked smart in a white trouser suitCredit: Rex
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Alex Jones turned heads on the red carpetCredit: Rex
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Chloe Burrows sent temperatures soaringCredit: Rex
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Adam Woodyat and Michelle Collins from EastEndersCredit: Goff
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Ashley James looked pretty in pinkCredit: Rex
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Susanna Reid appeared to be in high spiritsCredit: Rex
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Helen Flanagan sported a smoky eye lookCredit: Rex
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Ekin-Su put on a leggy displayCredit: Rex
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Diane Parish looked sensational in a green dressCredit: Getty
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Clive Myrie sported a pair of casual white trainersCredit: Getty
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Love Island's Tasha and Andrew were couple goalsCredit: Splash
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Ella Thomas left little to the imagination in a pink two-pieceCredit: Rex
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Angelica Bell looked chic in a green ruffled dressCredit: Rex
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Fleur East made a statement in oversized trousers and bracesCredit: Rex
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Olivia Attwood flashed her legs in a green dressCredit: Rex
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Rochelle Humes looked elegant in a red floor-length gownCredit: Rex
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Saffron Barker showcased her cleavage in a cutout dressCredit: Rex
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Vicky McClure looked trendy in a black gownCredit: PA
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Molly Rainford put on a busty display in a white gownCredit: Rex
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Scarlette Douglas posed with a hand on her hipCredit: Rex
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Molly Marsh and Zachariah Noble cosied up to one anotherCredit: Getty
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Faye Winter put on a show-stopping displayCredit: Rex
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Cherry Healey wrapped up with a black leather jacketCredit: Getty
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Claire Sweeney oozed retro beautyCredit: Rex
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Maura Higgins flashed her underboob in a very racy dressCredit: Rex
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Tina O’Brien looked sensational in a nude ruffled gownCredit: Rex
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Lenny Henry looked suave in a cream jacketCredit: Rex
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Amy Dowden beamed from ear-to-ear for photographersCredit: Rex
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Katie Piper looked elegant in a black gownCredit: Rex
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Podcasters George and Joe Baggs brought their mum Lisa alongCredit: Rex
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Tom Allen kept cool in a pair of black shortsCredit: Rex
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Anna Williamson stunned in a purple statement dressCredit: Rex
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Seann Walsh cut a dapper figure as he posed for snappersCredit: Rex
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Sam Thompson wore a pair of crocs to the swanky bashCredit: Rex
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Jamie Laing looked dapper in a black tuxedoCredit: Rex
NTAs 2023: the winners
Serial Drama
Coronation Street
EastEnders - Winner
Emmerdale
Hollyoaks
Talent Show
Britain’s Got Talent
Strictly Come Dancing - Winner
The Great British Bake Off
The Great British Sewing Bee
New Drama
Beyond Paradise
Blue Lights
Queen Charlotte: A Bridgerton Story
Wednesday - Winner
Daytime
Loose Women
The Chase
The Repair Shop - Winner
This Morning
Comedy
Brassic
Ghosts
Ted Lasso
Young Sheldon - Winner
Authored Documentary
Deborah James: Bowelbabe in Her Own Words
Lewis Capaldi: How I’m Feeling Now - Winner
Matt Willis: Fighting Addiction
Rob Burrow: Living with MND
Rising Star
Benjamin Chivers (Isaac, The Devil’s Hour)
Bobby Brazier (Freddie Slater, EastEnders) - Winner